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Xception704
March 27th, 2008, 11:43 PM
So this is the problem:

Write expressions for K for the following reactions:

a. P4 (s) + 5O2 (g) <----> P4O10 (s)

The equation for an equilibrium expression is K = [C]^c[D]^d
.................................................. ..............[A]^a[b]^b

Using this formula, I thought the answer would have been [P4O10]
.................................................. ...........................[P4][O2]^5

The back of the book says 1/[O2]^5

Anyone willing to explain to me why that is? I thought about if maybe they'd cancel, but that'd leave O10/[O2]^5

=\

MeaCulpa
March 28th, 2008, 12:56 AM
Solids and pure liquids don't show up in equilibrium expressions. It has something to do with the concept of activities and other thermodynamics stuff, but don't worry about that much. Just know that only concentrations of aqueous solutions and partial pressures (or concentrations) of gases are used in deriving expressions for K.

Xception704
March 28th, 2008, 01:13 AM
Oh wow. That's what I get for not reading my notes. Thanks. =)